afaik an AM2 Sempron should support standard DDR2 RAM just the same way as any
other desktop AM2 CPU, except some RAM frequency settings may not be available or incompatible.
You might want to study that in order to get both sticks running.
In BIOS Try to set the ram running @ DDR 667 or close to it, to start with.
http://en.wikipedia.org/wiki/DDR2_SDRAM
DDR800 = PC2-6400
DDR667 = PC2-5400
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