You could try deleting all your profiles from VECC then delete the .xml files in "C:\Users\YOU\AppData\Local\ATI\ACE\Profiles\yourprofilenames.xml"
RESTART.
Try creating again, maybe using different unique names for the profiles.
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#1: Phenom II C2 955BE @ 3.6, Antec Kuhler 920, Gigabyte GA-MA790FX-DS5, Asus 5870/V2, ASUS Xonar D2X, 4 x 1gig OCZ2N1066SR2GK @800, Antec Truepower New 750, Arc Midi, Win8pro x64 upgrade
#2: Athlon 64 X2 4200+, AGP 1950pro, Audigy 2, Asus A8V-D, 2gig ram, Enermax 465P, Antec900. Now on Win8pro cat 10.2